Cerium(III) chloride heptahydrate is used in the preparation of allylsilanes from esters. It is used as a reducing agent in organic synthesis in place of sodium borohydride. In Luche reaction, carvone gives selectively allylic alcohol.
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ApplicationsCerium(III) chloride heptahydrate is used in the preparation of allylsilanes from esters. It is used as a reducing agent in organic synthesis in place of sodium borohydride. In Luche reaction, carvone gives selectively allylic alcohol.
SolubilitySoluble in alcohol and acetone. Slightly soluble in tetrahydrofuran. Insoluble in cold water.
NotesAir sensitive. Hygroscopic. Incompatible with strong acids and strong oxidizing agents.